Oxidative dehydrogenation of n-butene to buta-1,3-diene with novel iron oxide-based catalyst: Effect of iron oxide crystalline structure
نویسندگان
چکیده
We investigate the effect of crystalline structure iron oxide catalysts on oxidative dehydrogenation (ODH) n-butene. ODH reactions n-butene were carried out with a fixed-bed flow reactor at 450 °C under but-1-ene (1-C4H8) or cis-but-2-ene (cis-2-C4H8)(mL/min)/O2(mL/min) ratio 5/2.5. Of various oxide-based (α-, β-, γ-, ε-Fe2O3, Fe3O4, ZnFe2O4), ε-Fe2O3 showed highest activity. To best our knowledge, has never been used for Moreover, catalytic performance was improved by adding SiO2, which is related to maintenance its and improves redox property. A high BD selectivity 65 % yield 18 then obtained 4 h without deactivation. This catalyst can be applied cis-2-C4H8 proposed as noble
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ژورنال
عنوان ژورنال: Molecular Catalysis
سال: 2021
ISSN: ['2468-8231', '2468-8274']
DOI: https://doi.org/10.1016/j.mcat.2021.111560